Prevention of wood discoloration

Prevention of wood discoloration

1

. Prevention of photochromism

If the surface of the wood has already produced photochromism, sanding or cutting can be used to remove the discoloration.

Floor. If the color changing layer is very light, bleaching can be used to remove the chromophoric compound from the surface, such as

Hydrogen peroxide, sodium chlorite, and the like. Wood that does not produce photochromism can be treated as follows:

(

1 ) Physical methods

The most used in physical methods is to cover the surface of the wood with a paint or varnish.

Degradation of wood components due to ultraviolet light and visible light only occurs on the surface of the wood, and the thickness is

0

. 075 _ 0 . 25 mm , so the paint method is used to form a film layer, which can effectively prevent the day.

Light irradiation prevents the occurrence of free radical degradation reactions. Simultaneously

i non-porous film layer can prevent external moisture

Infiltration, it can also improve the dimensional stability of wood and reduce the discoloration caused by the removal of wood extract.

Because paints have a wide range of colors to choose from, they are easy to apply and have good results, so people have long been

This method is widely used for furniture and decoration. However, the paint has poor transparency. Can't show perfection

Wood natural texture with color. Although varnish can make up for this defect, varnish is sensitive to water.

Strong, the film is brittle, easy to fall off, and has a short service life. No paint or varnish has anti-corrosion effect.

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2 ) Chemical methods

1 UV absorber. Treating wood surfaces with UV-containing coatings can effectively prevent

Light discoloration. Such as salicylic acid derivatives and

2 . a derivative of hydroxybenzoyl, etc., without color itself,

Absorbing wavelength at

Ultraviolet light below 400 urn .

2 Change the functional group of the wood component to destroy the structure of the substance involved in discoloration. Due to lignin

a

- The carbonyl group acts as a photosensitizer in the photodegradation of lignin and is the main color-developing structure, so it changes

This structure is an effective method to prevent photochromism. Methylation, acetate, and benzene are commonly used in wood.

A combination of acylation and oxidation or reduction, destroying the chromophores of wood and the precursors that cause discoloration

The material structure prevents the photodegradation of wood and the effect is very good. If the wood is treated with diazomethane,

a one

The carbonyl group is converted to ethylene oxide to increase its stability. These treatments also apply to wood caused by extracts

The material is discolored. Can change the aromatic ring side chain. The chemical reagents of a carbonyl structure mainly include: diazomethane, sulfur

acid

M methyl ester, acetic anhydride, benzoic acid, sodium borohydride, o-nitrobenzoyl, 3 , 5 - M nitrobenzoic acid

Acyl and the like. Polyethyl

M alcohol ( PEG ) coated wood, good resistance to wood with lighter color

Photochromism, but the effect on wood with darker wood is poor.

The relative molecular mass of PEG 1000

~

4 000 is appropriate. Studies have shown that after PEG absorbs light energy, it generates free radicals, forms free radicals and oxygen.

a peroxide that destroys the structure of the chromonic material and whitens the color of the wood, thereby inhibiting

The color of wood is discolored. In addition, chemical agents and preservatives that prevent discoloration of wood are also commonly used.

The agent and the dyeing agent are used together to improve the ultraviolet rays during the process of dyeing, anticorrosion and waterproof treatment.

The ability to block absorption. Some reagents with oxidation and complexation (such as chromium trioxide, copper chromate).

Semi-carbonitrile and its derivatives) and stabilizing metal salts (such as magnesium or alkaline earth metal sulphur)

Acidic acid, thiosulfate, and reduced compounds such as ascorbic acid) can be used to coat wood surfaces.

Prevent the initial discoloration of wood. These chemicals can be complexed or oxidized by chemical components of wood.

The role prevents the degradation reaction from occurring. It also improves the durability of coatings and colorants, while some reagents are also

Has antibacterial ability.

3 wood staining. In order to prevent the fading and discoloration of wood, some woods need to be used before they are used.

Dye coloring or coloring. Dyes can be divided into acid dyes, basic dyes, direct dyes and oils.

dye. Acid dyes are used more. Acid dyes dye lignin, not cellulose and

Hemicellulose staining. This effectively prevents lignin browning caused by photochemical degradation. dye

The color can be selected from the colors of some precious wood, such as mahogany, rosewood, ebony and so on. For staining

Evenly, the wood is generally pretreated with a dilute alkali solution (

1 % Naz CO ), remove surface extracts and phenols,

Again

Decolorization of HZQZ , followed by acid dyeing, can achieve uniform coloration and good light fastness

wood. In the wood dyeing process, the dye can be impregnated to a certain depth of wood, but does not form an independent

The coating can produce polar adsorption, hydrogen bonding or chemical reaction with components in the wood. therefore,

In use, sunlight, wind erosion or excessive moisture does not cause foaming or flaking on the surface of the dyed wood.

Therefore, the dyed wood is stable in color, has less degradation reaction, and is durable in materials. But because of wood

The structure of the tissue is densely arranged, so that the dye molecules are not easily penetrated into the depth of the wood. Under normal pressure, generally only

Shallow dyeing, re-processing color is not easy to retain. With pressurized treatment, it can only be used for difficult-to-penetrate materials.

Handle smaller components. The use of standing wood dyeing and veneer dyeing can make the colored layer deeper or evener.

But consider the effect of dyeing on gluing and finishing.

2

. Prevention and treatment of chemical reagent discoloration

(

1 ) Iron discoloration. Iron pollution is mostly caused by the surface of the sliced ​​or rotary cut veneer and its contact with the hot press

The part. For smaller areas of discoloration, it can be removed by planing or sanding; for large area changes

1 first brush it again

4% aqueous oxalic acid solution, then brushed with aqueous sodium dihydrogen phosphate solution, coated

Amount

10 g/m2 (more contaminated parts).

2 use

50 % hypophosphorous acid 20 g , 50 % sodium hypophosphite 2 g , 50 % sodium bisulfite 0j

g

, soluble in 90 mL of water is applied to the surface of the wood.

3 use

A 2 % to 5 % aqueous solution of oxalic acid is applied to the surface of the wood, dried and rinsed with water.

4 use

2 % to 5 % aqueous hydrogen peroxide solution applied to the surface of wood.

5 use

2 . A 5 % aqueous solution of hypophosphorous acid ( pH = 3 ) was applied to the surface of the wood, dried and rinsed with water.

5 in

In a 3 % aqueous solution of oxalic acid, add 0 . 5 % ethylenediaminetetraacetic acid, applied to the surface of wood,

It can prevent iron pollution.

1 Put the disodium salt of oxalic acid, ammonium dihydrogen phosphate and ethylenediaminetetraacetic acid into the pool of steamed logs

It can prevent iron pollution.

(

2 ) Acid discoloration. For wood treated with acid to remove iron contamination, it should be washed thoroughly or added with phosphoric acid.

Disodium hydrogen to prevent acid discoloration. For surface discoloration, it can be removed by shaving or sanding.

Chemical elimination

The method is as follows:

1 at

2o ~ 10 % aqueous hydrogen peroxide solution, add people. Ammonia water, call out 7 . 0 _ 8 . 0 ,

Applied to a contaminated surface;

3 will

0 . 2 % to 2 % aqueous sodium chlorite solution, adjusted to weakly alkaline, applied to the contaminated surface;

3 will

0 . 1 % ~ l % sodium borate aqueous solution, adjusted to weakly alkaline, applied to the contaminated surface.

(

3 ) Alkali discoloration. Alkali discoloration often occurs on the surface of phenolic resin plywood, often in contact with cement

The surface of the wood and the surface of the wood treated with a strong alkaline bleach.

Initial alkali contamination can be removed by aqueous shikimic acid solution

The concentration should be determined by the degree of contamination. If dirty

The dyeing time is longer. Then change the concentration to

2 % to 10 % hydrogen peroxide treatment

3

. Prevention of blue discoloration

The anti-blue-modifying compound with excellent performance should have broad-spectrum activity, low toxicity, and easy preparation and use.

Low cost features. There are many factors affecting the properties of anti-blue-induced compounds, including broad-spectrum activity and various killings.

Combination of microbial agents, interaction between fungicides and wood components, tree species, storage after treatment

Condition, the environmental conditions for the use of wood, etc.

For a long time, wood anti-blue coloring agents are mainly sodium pentachlorophenol and sodium tetrachlorophenol. Such drugs for prevention

Microbiological hazards are very effective and are broad-spectrum antibacterial agents. But these more toxic drugs

Agents have many adverse effects on humans and the environment. Therefore, the currently used antiseptic and anti-tarnish agents

Toxicity has increasingly caught the attention of researchers. The use of such agents has been banned in some countries in the United States and Northern Europe. With the advancement of human beings and the deep research of human beings, some preservatives with high toxicity and easy loss will stop.

J

Use, new and non-toxic high-efficiency preservatives and new anti-corrosion routes are urgently needed. Used in recent years

Some anti-tarnish agents are described as follows:

(

1) 8-hydroxyquinoline Cu (Copper-8), copper naphthenate (Copper Naphthenate), 2 -

Methylthiobenzothiazide thiocyanate

TCMTB ) and boride (boric acid and borax, Timhor )

These are the second generation of wood anti-blueing agents after sodium pentachlorophenol and sodium tetrachlorophenol. Its toxicity.

Sodium pentachlorophenolate and sodium tetrachlorophenol. Various forms

8 -hydroxyquinoline copper has properties for organic organisms.

Bactericidal effect, such as

5.4 active ingredient 8 - hydroxyquinoline copper PQ8, its anti-blue change '

The anti-mildew effect is higher than that of sodium tetrachlorophenol. For new substitutes, the effect is sustainable.

12 months, brushing, spraying

Washing and immersing the wood,

PQ - processing amount of 8-hydroxyquinoline is 8 a copper surface of the wood 7-9

Ug/cm2

. ECOBTITE is an anti-blue agent composed of borax and Na2CO3 , which is non-volatile and environmentally friendly.

Non-polluting, non-toxic to humans and animals, non-corrosive to metals, low cost, diffusion of wet wood

Good sex, poor resistance to loss, anti-blue color effect is lower than sodium pentachlorophenol and sodium tetrachlorophenol, and in wood

The enzyme compound chemically reacts to produce browning. Contain

30% TCMIB active ingredient can be made

Water forming agent

Busan30WB and oil . The test results show that the surface of the newly cut wood is sprayed

Shi

40 to 50 ug/cm2 ; The wood remained intact for 12 months. Treatment surface TC-

MTB

The amount of retention can be accurately detected by high performance liquid chromatography for quality control. Not touching the soil

Wood,

The corrosion resistance and mildew resistance of TCMT can reach more than 10 years, and TCMTB is resistant to blue;

The problems in the skin are irritation to the skin and toxicity to fish.

(

2 ) 3 -iodo- 2 -propynyl methionine ( IPBC )

Season hinge salt

DDA and other fungicides are third-generation wood anti-blue colorants, which are anti-blue color

Very effective active ingredient of the agent. It can be formulated into oil-soluble and water-soluble formulations. Oil soluble

The most commonly used preservative for impregnated joinery is the finely divided formula

3 -iodo- 2 -propynylmethylammonium

Butyrate

IPBC) and dimethyl dikutyl chloride (DDAC ) are used to control new saw sheets. (Such as low, has been registered in many countries (

United States and Japan).

IPBC is also widely used as a fungicide for coatings and as an auxiliary sterilization.

Used in combination with other chemicals for wood preservatives in contact with soil.

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3 ) Dimethyldiindenyl chloride hinge ( DDAC )

It is an efficient broad-spectrum fungicide and is the most promising wood antiseptic and anti-tarnishing agent. Correct

The village has a natural affinity and can be fixed in wood by cation exchange, but exposed to acidity.

Under the piece (such as acid rain) its effect is significantly reduced. This drug fixation is slower, sometimes up to

2 weeks

Timbercote

, NP - 1 and F - 2 has been registered for use in Canada, the United States, and some European countries. Pick

In use, it is effective against blue, and it can protect the surface and interior of wood. Anti-blue change, antiseptic

NP

- 1 is currently the most widely used anti-blue variant in North America. It is a mixture of JPBC and DDAC with a wide range of bactericidal properties. DDA has the role of surfactants and coupling agents, IPBC and

DDA

It has synergistic bactericidal properties and improved resistance to bleed. NPI XitH pine mushroom fungi, blue

Variable bacteria have a good effect

Suitable for pine and eucalyptus. F - 2 is an emulsifier effective concentrated

Ingredients are

DDA and disodium octaborate tetrahydrate. Dispersion of disodium octaborate into wood prevents wood

Decay,

F-2 has a factory poisoning effect on mold and decay fungi, and the antiseptic effect is equivalent to that of chlorinated phenol.

F

- 2 needs to be diluted in use. Spray elbow The concentration of DDAC is 2 % to 5 % DDA thick when soaking

Degree

1%-2% DDAC has contact toxicity.

(

4) three class file (Propiconazole)

Triterpenoids

azaconazole) and Tai Bukang file (Tebuconazole) of nitrogen-containing

A new class of wood resistant to blue and antiseptic agents.

Active ingredients of Rodewod 200EC

for

Azaconazole , contains 0 . 8% azaconazole of Rodewod 200EC effect and contain

1

. The effect of 0 % sodium pentachlorophenolate is comparable. Rodewod 200EC 's acute oral death in mice and rabbits

The amount is

1291 rn / kg and 2190 mg / kg , the toxicity is very low. AP143 is an emulsion,

contain

1: 1 Azaconazole and IPBC active ingredient, the highest concentration is 5 % AP - 143 available dip

The bubble method and the spray method treat a variety of woods, and the anti-blue color effect is good under various climatic conditions.

2 %

AP

- 143P anti-blue effect on Douglas fir and Chinese fir 2 % Busan 1030 is the same, 0 . 2 %

of

AP - 143 anti-blue effect ratio of radiated pine sapwood 1 . 0 % NP-1 and O. 4 % Busan

30WB

The effect is good. AP143 has a slight odor, cleans the surface of the wood, and has a mammal

Moderately toxic, low to skin irritation and irritating to the eyes.

Rodewed 300SC - TU contains

The active ingredients are triterpenoids and chlorothalonil (

w : W = 1 : 1 ) mixture, triterpenoids have good

Anti-blue effect, chlorothalonil inhibits mold very effectively, so

Rodewod 300SC-TU can effectively prevent

The blue and mildew of the newly cut wood and the untreated logs are also inhibited by decay. Follow the United States and

European test methods have shown that Taibu Kangxi has effective defense against basidiomycetes of decaying wood.

The effect of treatment, especially on brown rot fungus and white rot fungus. Tabu Kang has low water

Solubility, high stability to heat and light, and miscibility with other active ingredients. For mammals, fish and algae

It is biotoxic and biodegradable.

5 chlorothalonil (

Chlorohalonil ) ( 2 , 4 , 5 , 6 - tetrachloro - 1 , 3 - benzoquinone )

Chlorothalonil is one of the broad-spectrum fungicides used in recent years. Used in the United States

35 crops, low

Toxic, does not cause mutations in mammalian genes. Solubility in water is

0 . 6 x 10 - 6 , dimethylformamide

(

The solubility in DMF is 3/kg and in dimethyl sulfoxide ( DMSO ) is 2/kg in xylene.

for

8 lkg , does not accumulate in the soil. In 1993 , the American Wood Preservative Association ( AWPA ) will bring chlorothalonil

Officially listed

AWPA oil-soluble preservative standard P - 8 . In recent years, chlorothalonil preparations have been widely used to prevent wood.

Wood mold

Studies on color-changing bacteria, wood rot fungi, and terrestrial termites.

Effective chlorothalonil preparation for preventing mold

6 : 1 . 0 % chlorothalonil WP,

0

. 50% chlorothalonil ten 0. 5 % Azaconazole ; 1 . 0 % chlorothalonil emulsion, 0 . 50 % chlorothalonil +0 . 50 % DDA , 0 . 50% chlorothalonil ten 0. 10 % IPBC and 0 . 50 % chlorothalonil wettable powder

Agent ten

0 . 50 % 8 -hydroxyquinoline copper. They and 0 . 40 % NaPCP has the same anti-mildew effect. Prevent

Effective chlorothalonil preparations for color-changing bacteria mainly

0 . 50% chlorothalonil ten 0. 50 % DDA . 1 . 0 %

Mycelium clearing agent,

0 . 50% chlorothalonil ten 0. 10 % IPat, etc., to prevent the effect of color-changing bacteria 1 . 0 %

NaPCP

quite. Chlorothalonil is also used as a wood preservative, as an additive to CCA , to change the anti-corrosion material &

Mildew

It is the preferred agent for electric pole anti-corrosion. Treated with three concentrations of chlorothalonil and pentachlorophenol oil solution

loose

Ponderosa pine poles after 8 years of field tests show that the same effect termite preservative concentration than pentachloropropane

phenol. Loss tests show that the fixation is superior to pentachlorophenol and is environmentally safe. Chlorothalonil and poisonous monument

Chlorpyrifos

a mixture of ( O , O -diethyl- O3 , 5 , 6 -trichloro- 2 -pyridylsulfate)

Has good anti-wood rot and anti-termite performance, is

Alternative to NaPCP, chloroemulsion type

Use will reduce the cost of preservatives.

4

. Prevention of other discoloration

*) Thermal discoloration. In order to prevent the drying bow

l discoloration of wood, can be coated with sulfurous acid before drying

Chemical tests for sodium, sodium bisulfite, ascorbic acid, semicarbazide, urea, semicarbazone and zinc oxide

These can effectively prevent thermal discoloration. In addition, use organic solvents or hot water to treat wood before discoloration.

material

Start to reduce the thermal discoloration of wood. For wood that has produced thermochromism, a planing method can be used.

The color changing layer is removed because the thermal discoloration is almost limited to the surface. Bleaching agent oxidative decomposition method

Remove, such as repeated brushing of the material with alkaline hydrogen peroxide or sodium chlorite solution.

(

2 ) Enzymatic discoloration. Coating wood with chemicals such as dilute acid or sulfite, or boiling wood with boiling water

Or microwave radiation treatment, these can destroy the living conditions of the enzyme and prevent the wood enzyme from discoloring. In addition, in

When dealing with wood, add antioxidants, such as

2 , 4 , 6 -trimethylbenzoic acid and other antioxidants are soluble

In the organic solvent, the surface of the wood is also rubbed to inhibit the discoloration of the enzyme.

For wood that has produced enzyme discoloration, it can be bleached or hot water extracted by hydrogen peroxide or the like.

Remove.

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